https://nova.newcastle.edu.au/vital/access/ /manager/Index en-au 5 Cyclodextrins grafted MoS2/g-C3N4 as high-performance photocatalysts for the removal of glyphosate and Cr (VI) from simulated agricultural runoff https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:39073 2/g-C3N4 based photocatalysts remains a major hurdle to their successful application for the remediation of water-soluble contaminants such as herbicides and heavy metals. Herein, we develop new photocatalysts based on the graft of three different cyclodextrins (α-CD, β-CD and γ-CD) on MoS2/g-C3N4 composites (CDs/MoS2/g-C3N4) for the removal of glyphosate and Cr (VI) from simulated agricultural runoff. CDs/MoS2/g-C3N4 show remarkably enhanced photocatalytic activities for glyphosate degradation and Cr (VI) reduction compared to pristine MoS2/g-C3N4. In addition, γ-CD/MoS2/g-C3N4 exhibits the highest hydrophilicity and photocatalytic activity among these three different cyclodextrins grafted MoS2/g-C3N4. The mechanistic investigation indicates that cyclodextrins can not only increase the accumulation of glyphosate and Cr (VI) onto the surface of CDs/MoS2/g-C3N4 but also facilitate the fleet separation of photo-induced electron-hole pairs. In summary, these results collectively imply that the graft of cyclodextrins could be an effective strategy to improve the photocatalytic efficiency of MoS2/g-C3N4 composites for the removal of glyphosate and Cr (VI) from simulated agricultural runoff.]]> Wed 04 May 2022 15:10:42 AEST ]]> Enhancing prediction accuracy of physical band gaps in semiconductor materials https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:53200 Fri 17 Nov 2023 12:04:28 AEDT ]]> Adsorption of O and Cl on Tl/Si(111) - suppressed spin polarization via bilayer formation https://nova.newcastle.edu.au/vital/access/ /manager/Repository/uon:38432 Fri 10 Sep 2021 14:50:32 AEST ]]>